Computers are not that great at creating random numbers as the methods they use are deterministic. That is, they start from a number (called a seed) and apply maths to that number to generate pseudorandom numbers. Most random numbers generated by computers programs use a seed provided by the system, which is generally the current time. If you can guess the initial value then you can start to work out what the random sequence of numbers generated is. Most random numbers, are therefore not suitable for encryption.
To get a random row from a Microsoft SQL database you need to use the NEWID() function. This will generate a new random number for each row and order them by that new number. This is used in conjunction with the TOP clause to limit the amount of returned rows to one.
SELECT TOP 1 VALUE FROM TABLE ORDER BY NEWID()